: , , ..

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- -
322


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( Gallia-, . . ; . Gallium) Ga, . III . . , . . 31, . . 69,72. . . ...

, Ga; - Gn3_n, R = Alk, Ar; X = = Hal, .; = ...

( ) GaSb, . , ( = 0,609593 ); . . 712; . ...

GaAs, - . , ( = 0,565321 ); . . 1238; . ...

. . - . . G13-. [ 0,694 , b = 0,684 ...

. Ga2O3- . . - 123 (a = 1,223, b = 0,304 , = = ...

GaP, - ; ( = 0,54495 ); . . 1790- . ...

(3,4,5- -), . . 170,11. , 100-120 ; . , ; . . 220 ...

. ,,. . . . -, ...

(), . . - RC(O)Hal. - (. .), - ( - ...

. . -, - -, - . .- - (. .); . , ...

, . ., - , (., . ). ...

, . . . . . ., - , . . ...

(), . . - ( .) ( .). . . ...

, . . . . . - ...

( ), 50% Na, , () Mg. . ...

, (1, , I), . , . ,. ...

(), . ., . . . . ...

, . ()n(S)13_n, = 1, 2; R = Alk, Ar, , SiAlk3; Hal = F, Cl, Br ( ...

, . - ()n()13_n, = 1,2; R-op. ; Hal-F, C1, r (. Hal = I ). -. ...

, . - RnPHal3_n, = 1,2; R-op. . ; 98-102 (. ...

, . - (RO)nPHal3_n, R-op. ; Hal = F, Cl, Br (. Hal = I ); = ...

( ), . - n, 1, 3 5. IF7, C12F2 ...

() HalCN, . . . . . . (C1CN BrCN) (ICN). ...

( . hals, . halos - -genes-, []) (), . VII . . : ...

( ), ., , ( ) -, - ...

, . . ...

( . hals- ergon-, , - ), . , - . ...
-
- , . . ...

, . , . ( ). . ., ...
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